Skin-safe, flexible photodetectors combine graphene and carbon dots for wearable sensing
Researchers from Ca’ Foscari University of Venice, working within the SUPERVenice research unit, have developed a new type of flexible, skin-compatible photodetector that can sense light across a broad range of wavelengths while operating at low voltage and remaining safe for direct contact with human skin. The device, reported in Advanced Functional Materials, combines graphene with specially engineered carbon dots on a plastic substrate, creating a lightweight and bendable photodetector suitable for wearable electronics and on-skin sensing applications. Addressing a key challenge in wearable optoelectronics Photodetectors—devices that convert light into electrical signals—are essential components in technologies ranging from cameras and optical communications to medical sensors. Conventional photodetectors, often based on rigid silicon electronics, perform well but are poorly suited for wearable or skin-integrated systems, where flexibility, low power consumption and biocompatibility are crucial. Many flexible photodetectors reported to date compromise on at least one of these requirements. Some offer high sensitivity but rely on toxic materials such as lead- or cadmium-based quantum dots; others are flexible but operate over a narrow spectral range or lack evidence of skin safety. The new work addresses these limitations by combining broadband optical response, mechanical flexibility and verified skin compatibility within a single device architecture. Carbon dots and graphene: complementary roles The photodetector is built by integrating hydrothermally synthesized carbon dots with single-layer graphene transferred onto a polyethylene terephthalate (PET) substrate. The carbon dots act as the light-absorbing element, while graphene provides an efficient, high-mobility pathway for charge transport. Unlike conventional quantum dots, the carbon dots used in this study are metal-free, environmentally benign and inherently biocompatible. By carefully tuning their synthesis conditions, the researchers engineered the dots to absorb light not only in the ultraviolet but also across the visible and near-infrared range, extending roughly from 400 to 800 nanometers. Graphene alone absorbs only a small fraction of incoming light, but when coupled to the carbon dots it efficiently collects photogenerated charge carriers, enabling a measurable electrical response across the full spectral window. Low-voltage operation with a biopolymer gate To control the device electronically, the team used a chitosan–glycerol biopolymer electrolyte as a gate dielectric. Chitosan, derived from natural sources such as chitin, is non-toxic and widely used in biomedical applications. This electrolyte enables strong electrostatic gating at very low operating voltages, with optimal performance reached at around 0.5 V, well below the levels typically required by flexible photodetectors. Under illumination, the device shows a gate-dependent photoresponse that can be tuned between different operating regimes, with peak responsivities of approximately 0.19 A/W at 406 nm, 0.32 A/W at 642 nm, and 0.18 A/W at 785 nm. Performance under bending and repeated use Mechanical flexibility is a key requirement for wearable electronics, and the researchers subjected their devices to extensive bending tests. The photodetectors maintained stable operation at bending radii as small as 0.8 cm and showed no significant degradation after up to 1000 bending cycles. The response times, on the order of one second, are compatible with many wearable sensing applications, including biometric monitoring and environmental light sensing. Demonstrated skin compatibility Beyond electrical and mechanical performance, the study directly addresses skin safety, an aspect often assumed rather than tested in wearable optoelectronics. Using reconstructed human epidermis models and fibroblast cultures, the researchers showed that neither the complete device nor its individual components caused skin irritation or cytotoxic effects. Importantly, illumination under realistic operating conditions did not induce detectable reactive oxygen species (ROS) generation, indicating that the device is photo-safe for on-skin use. Toward practical wearable photonics While the device is presented as a proof of concept, the authors emphasize that the materials and fabrication steps are compatible with scalable, low-cost processing. Future work will focus on improving detectivity, optimizing large-area uniformity, and integrating the photodetectors into functional wearable platforms. By combining metal-free light absorbers, graphene electronics, biopolymer gating and direct biological testing, the study outlines a practical route toward next-generation photodetectors designed from the outset for safe, wearable operation. The full study is published in Advanced Functional Materials and is available at https://doi.org/10.1002/adfm.202523076
Skin-safe, flexible photodetectors combine graphene and carbon dots for wearable sensing Read More »









